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Alisa_LGA
United Kingdom
3 Posts |
Posted - 10/21/2018 : 05:04:32 AM
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Hi guys! Could you please help me to find an approximation of experimental data with the non-linear equation:
k1*y+k2*x+ln((k3*x)/(x-y))-k4=0
I need to find constants k1,k2,k3 and k4. I know a set of values (around 100 values) for x andy.
Which function should I use in Origin to find the constants?
Any of your replies are very appreciated!
Origin Ver.2018 and Service Release (Select Help-->About Origin): Operating System:Win 10, 64
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yuki_wu
896 Posts |
Posted - 10/22/2018 : 02:22:17 AM
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Hi,
Would you like to perform fitting on your dataset? If so, you could defiend a user-defined fitting function first and then perform fitting using that function. Please take a look at this page, it should help: https://www.originlab.com/doc/Tutorials/UserDef-FitFunc
Regards, Yuki
OriginLab
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Alisa_LGA
United Kingdom
3 Posts |
Posted - 10/24/2018 : 09:57:55 AM
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Hi, thank you for the reply! But unfortunately, it just does not want to fit the data and optimize the constants. I checked everything manually (put the guess values into the column) and it calculates fine. But the non-linear curve fit gives me: "(4) Fit did not converge - reason unknown."
Please see the attached image.
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Alisa_LGA
United Kingdom
3 Posts |
Posted - 10/24/2018 : 11:26:34 AM
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quote: Originally posted by yuki_wu
Hi,
Would you like to perform fitting on your dataset? If so, you could defiend a user-defined fitting function first and then perform fitting using that function. Please take a look at this page, it should help: https://www.originlab.com/doc/Tutorials/UserDef-FitFunc
Regards, Yuki
OriginLab
Moreover, I found that Origin cannot describe the combination of exponential functions at all.
When I built a combination of 2 exponential functions (with known parameters), I cannot describe it with the same formula unless I am putting exactly those parameters I inserted.
P.S. Sometimes, it cannot be described even with the same parameters initially inserted.
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yuki_wu
896 Posts |
Posted - 10/25/2018 : 02:23:56 AM
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Hi,
1# Please take a look at this page to find the reason why fail to converge: https://www.originlab.com/doc/Origin-Help/The_Reason_Why_Fail_to_Converge
2# I am sorry I don’t understand your question, but you could definitely define a fitting function with multiple exponential functions in Origin, for example, the built-in functions ExpGro2, ExpGro3 and etc. You could press F9 to open Fitting Function Organizer and expand Exponential tree node to look up the functions I mentioned.
Regards, Yuki
OriginLab
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Edited by - yuki_wu on 10/25/2018 02:32:37 AM |
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