Spaces within a reference string are problematic and how you handle them may depend on what browser you are using.
In IE7 (haven't tried 6), you must protect the spaces with quotes :
win -aw "file://C:/Program Files/OriginLab/OriginPro75/help.htm";
but this does not work if Firefox is your default browser. In that case you will need to use short names for those folders with space characters, as in :
win -aw file://C:/Progra~1/OriginLab/OriginPro75/help.htm;
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