You can only fit one function for every fitting session. However, you can use the Data Selector tool to select different part of the curve to fit different functions.
With version 7.x Pro, you can use PFM to perform such mixed-function fitting on single dataset
With 8.0 you need SR1 that has Peak Fit Wizard and that allows fitting with mixed functions as well. This functionality is being improved in upcoming SR2.
If you have standard version, then you can fit individual ranges as Larry suggested.